3520-15-8Relevant academic research and scientific papers
Selective Electrochemical Hydrolysis of Hydrosilanes to Silanols via Anodically Generated Silyl Cations
Liang, Hao,Wang, Lu-Jun,Ji, Yun-Xing,Wang, Han,Zhang, Bo
supporting information, p. 1839 - 1844 (2020/12/01)
The first electrochemical hydrolysis of hydrosilanes to silanols under mild and neutral reaction conditions is reported. The practical protocol employs commercially available and cheap NHPI as a hydrogen-atom transfer (HAT) mediator and operates at room temperature with high selectivity, leading to various valuable silanols in moderate to good yields. Notably, this electrochemical method exhibits a broad substrate scope and high functional-group compatibility, and it is applicable to late-stage functionalization of complex molecules. Preliminary mechanistic studies suggest that the reaction appears to proceed through a nucleophilic substitution reaction of an electrogenerated silyl cation with H2O.
Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines: A Theoretical and Experimental Approach
Bellini, Clément,Carpentier, Jean-Fran?ois,Tobisch, Sven,Sarazin, Yann
supporting information, p. 7679 - 7683 (2015/06/25)
Alkaline-earth (most prominently barium) complexes of the type [Ae{N(SiMe3)2}2(THF)x] and [{N^N}Ae{N(SiMe3)2}(THF)x] are very active and productive precatalysts (TON=396, TOF up
SILYL-BENZIMIDAZOLO[1,2-A]BENZIMIDAZOLE AS HOST FOR ORGANIC LIGHT EMITTING DIODES
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Page/Page column 61; 62, (2015/11/17)
The present invention relates to compounds of formula (I) and their use in electronic devices, especially electroluminescent devices. When used as hole transport material in electroluminescent devices, the compounds of formula (I) may provide improved eff
p-Bis(diphenylhydrosilyl)benzene. A useful Reagent for the Deoxygenation of Alcohols via Acetates
Sano, Hiroshi,Takeda, Toshimitsu,Migita, Toshihiko
, p. 119 - 122 (2007/10/02)
Acetates which were derived from primary, secondary, and tertiary alcohols were deoxygenated to the corresponding hydrocarbons in high yield by p-bis(diphenylhydrosilyl)benzene under homolytic conditions.
