352015-01-1

Basic information

• Product Name: Benzenemethanol, a-[(1R)-1-[[(2-hydroxy-5-nitrophenyl)methylene]amino]ethyl]-2-methoxy- a-(2-methoxyphenyl)-
• CAS NO: 352015-01-1
• Molecular Formula: C24H24N2O6
• Molecular Weight: 436.464
• Mol File: 352015-01-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[(1R)-1-[[(2-hydroxy-5-nitrophenyl)methylene]amino]ethyl]-2-methoxy- a-(2-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[(1R)-1-[[(2-hydroxy-5-nitrophenyl)methylene]amino]ethyl]-2-methoxy- a-(2-methoxyphenyl)-(352015-01-1)
• EPA Substance Registry System: Benzenemethanol, a-[(1R)-1-[[(2-hydroxy-5-nitrophenyl)methylene]amino]ethyl]-2-methoxy- a-(2-methoxyphenyl)-(352015-01-1)

Safety Data

• Hazardous Substances Data: 352015-01-1(Hazardous Substances Data)

Upstream product

• 16750-63-3 2-methoxyphenylmagnesium bromide 
• 352015-03-3 (R)-2-amino-1,1-di(2-methoxyphenyl)-1-propanol 
• 97-51-8 5-Nitrosalicylaldehyde 

Downstream Products

• 97-41-6 ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate 

Relevant articles and documents

Highly efficient chiral copper Schiff-base catalyst for asymmetric cyclopropanation of 2,5-dimethyl-2,4-hexadiene

A remarkable increase in catalytic activity is found for the asymmetric cyclopropanation of 2,5-dimethyl-2,4-hexadiene with diazoacetate by use of the chiral copper Schiff-base complexes, which are derived from substituted salicylaldehydes, chiral aminoalcohols, and copper acetate monohydrate. Furthermore, a combination of a chiral copper Schiff-base with a Lewis acid showed an increase in yield (up to 90%) and in enantioselectivity (up to 90% ee) for the asymmetric cyclopropanation of the diene with t-butyl diazoacetate at 20°C.