352353-66-3

Basic information

• Product Name: 2,2-dibromo-2-germatranyl-1-phenyl-1-ethanone
• CAS NO: 352353-66-3
• Molecular Weight: 495.691
• Mol File: 352353-66-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-dibromo-2-germatranyl-1-phenyl-1-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dibromo-2-germatranyl-1-phenyl-1-ethanone(352353-66-3)
• EPA Substance Registry System: 2,2-dibromo-2-germatranyl-1-phenyl-1-ethanone(352353-66-3)

Safety Data

• Hazardous Substances Data: 352353-66-3(Hazardous Substances Data)

Upstream product

• 128-08-5 N-Bromosuccinimide 
• 72077-70-4 1-(phenylethynyl)germatrane 

Relevant articles and documents

New approach to 1-(phenylethynyl)germatranes and 1-(phenylethynyl)-3,7,10-trimethylgermatrane. Reactions of 1-(phenylethynyl)germatrane with N-bromosuccinimide and bromine

Reaction of N(CH2CHRO)3GeBr (2a, b) with LiCCPh affords N(CH2CHRO)3GeCCPh (1a, b) (a, R=H; b, R=Me). Compound (1b) was also obtained by treatment of Cl3GeCCPh (3) with N(CH2CHMeOSnEt3)3 (4). (1a) reacts with N-bromosuccinimide to yield N(CH2CH2O)3GeC(Br)2C(O)Ph (5). Cis-N(CH2CH2O)3GeC(Br)=C(Br)Ph (6) is formed by the reaction of 1a with Br2 in equivalent amounts. All compounds were characterized by 1H- and 13C-NMR spectroscopy and mass spectrometry. Single crystal structures of 1a and 6 were determined by X-ray diffraction studies.