352354-05-3Relevant academic research and scientific papers
Impact of ligand exchange in hydrogen production from cobaloxime-containing photocatalytic systems
McCormick, Theresa M.,Han, Zhiji,Weinberg, David J.,Brennessel, William W.,Holland, Patrick L.,Eisenberg, Richard
, p. 10660 - 10666 (2011)
Ligand exchange on the Co(dmgH)2(py)Cl water reduction catalyst was explored under photocatalytic conditions. The photosensitizer fluorescein was connected to the catalyst through the axially coordinated pyridine. While this two-component compl
Organocobaloximes with mixed dioxime equatorial ligands: A convenient one-pot synthesis. X-ray crystal structures of BnCoIII(dmgH)(dpgH)Py and BnCOIII(chgH)(dpgH)py
Gupta,Yamuna,Singh, Veena,Tiwari, Usha,Barclay,Cordes
, p. 80 - 92 (2007/10/03)
A simple and general route to the synthesis of organocobaloxime with mixed dioxime ligands, RCo(dmgH)(dpgH)Py and RCo(chgH)(dpgH)Py, has been described. The 13C-NMR chemical shifts have been analysed to see whether one dioxime wing has any effect on the other dioxime wing. The first crystal structure of an organocobaloxime with mixed dioxime ligand in the same complex, BnCo(dmgH)(dpgH)Py and BnCo(chgH)(dpgH)Py, is reported.
