35244-03-2Relevant articles and documents
Syntheses of vinyl polymers containing phenylanthracene pendants and their application ro organic EL device
Shirai, Satoshi,Kido, Junji
, p. 386 - 387 (2002)
Fluorescent vinyl polymers containing 9-phenylanthracene pendants were synthesized and examined as an emitter layer in organic electroluminescent devices. The single layer polymer EL device using the homopolymer emitted green light originating from the ex
Unusual: Cis and trans architecture of dihydrofunctional double-decker shaped silsesquioxane and synthesis of its ethyl bridged π-conjugated arene derivatives
Walczak,Januszewski,Majchrzak,Kubicki,Dudziec,Marciniec
supporting information, p. 3290 - 3296 (2017/07/12)
Double-decker silsesquioxanes have gained a high reputation in many branches of chemistry and process development. In particular, catalytic processes that convert double-decker silsesquioxanes into important functional classes of fine chemicals are a central topic of contemporary organosilicon chemistry. Although the 9,19-di(hydro)octaphenyl double-decker silsesquioxane (DDSQ-2SiH) is known, we report its cis and trans structure and X-ray structure for the first time. The combination of DDSQ-2SiH in a known hydrosilylation reaction protocol with precise reaction time control (FT-IR in situ apparatus) allowed us to selectively assemble a series of previously unreported molecular double-decker silsesquioxanes with ethyl bridged π-conjugated arenes. These compounds were used as a molecular model to obtain their respective macromolecular hybrid analogues. The obtained compounds were characterized spectroscopically and their thermal parameters were also verified.
Rhodium-catalysed anomalous dimerization of styrenes involving the cleavage of the ortho C-H bond
Tobisu, Mamoru,Hyodo, Isao,Onoe, Masahiro,Chatani, Naoto
supporting information; experimental part, p. 6013 - 6015 (2009/05/06)
The dimerization of styrene derivatives in the presence of a rhodium catalyst proceeds to give stilbene derivatives, in which the ortho C-H bond of styrenes is cleaved and functionalized. The Royal Society of Chemistry.