352526-07-9

Basic information

• Product Name: [((p-cyanophenyl)-S₂C₂H)(bis-(diphenylphosphino)ethan)nickel(II)]
• CAS NO: 352526-07-9
• Molecular Weight: 648.391
• Mol File: 352526-07-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [((p-cyanophenyl)-S₂C₂H)(bis-(diphenylphosphino)ethan)nickel(II)](CAS DataBase Reference)
• NIST Chemistry Reference: [((p-cyanophenyl)-S₂C₂H)(bis-(diphenylphosphino)ethan)nickel(II)](352526-07-9)
• EPA Substance Registry System: [((p-cyanophenyl)-S₂C₂H)(bis-(diphenylphosphino)ethan)nickel(II)](352526-07-9)

Safety Data

• Hazardous Substances Data: 352526-07-9(Hazardous Substances Data)

Upstream product

• 14647-23-5 1,2-bis(diphenylphosphino)ethane nickel(II) chloride 
• 176037-45-9 4-(2-thioxo-1,3-dithiol-4-yl)benzonitrile 

Relevant articles and documents

Synthesis of heteroleptic nickel(II) and palladium(II) dithiolenes

Deprotection of 4-(p-cyanophenyl)-1,3-dithiole-2-thione, 4-(2-thienyl)-1,3-dithiole-2-one (1) and 4-(3-thienyl)-1,3-dithiole-2-one (2) with a base in MeOH or KOH and the posterior addition of nickel(II) and palladium(II) complexes give the formation of heteroleptic dithiolenes with 1,2-bis(diphenylphosphino)ethane, dppe, as an additional ligand. The X-ray analyses of two Pd-dithiolenes show a planar five-membered ring involving the metallic center and the dithiolene unit.