35274-18-1

Basic information

• Product Name: N-(4-chlorophenyl)propanethioamide
• CAS NO: 35274-18-1
• Molecular Formula: C₉H₁₀ClNS
• Molecular Weight: 199.7004
• Mol File: 35274-18-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 275.1°C at 760 mmHg
• Flash Point: 120.2°C
• Density: 1.257g/cm³
• Vapor Pressure: 0.00519mmHg at 25°C
• Refractive Index: 1.641
• CAS DataBase Reference: N-(4-chlorophenyl)propanethioamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-chlorophenyl)propanethioamide(35274-18-1)
• EPA Substance Registry System: N-(4-chlorophenyl)propanethioamide(35274-18-1)

Safety Data

• Hazardous Substances Data: 35274-18-1(Hazardous Substances Data)

Upstream product

• 2759-54-8 N-(4-chlorophenyl)propionamide 

Downstream Products

• 17142-83-5 6-chloro-2-ethylbenzo[d]thiazole 

Relevant articles and documents

Organocatalytic syntheses of benzoxazoles and benzothiazoles using aryl iodide and oxone via C-H functionalization and C-O/S bond formation

An organocatalytic protocol for the syntheses of 2-substituted benzoxazoles and benzothiazoles is described from alkyl-/arylanilides and alkyl-/arylthioanilides using 1-iodo-4-nitrobenzene as catalyst and oxone as an inexpensive and environmentally safe terminal oxidant at room temperature in air via oxidative C-H functionalization and C-O/S bond formation. The procedure is simple and general and provides an effective route for the construction of functionalized 2-alkyl-/arylbenzoxazoles and 2-alkyl-/arylbenzothiazoles with moderate to high yields. The synthetic and mechanistic aspects have been described.