35301-62-3

Upstream product

• 5806-90-6 N-methoxyacetamide 
• 71-43-2 benzene 
• 1795-83-1 N-Phenylacetohydroxamic acid 
• 54542-07-3 1-phenyl-propan-1-one-O-methyl-oxime 
• 186581-53-3 diazomethane 
• 134810-88-1 O-phenylethanoyl-N-phenyl-acetohydroxamic acid 
• 134810-87-0 N-isopropylacetoxyacetanilide 
• 134810-86-9 N-Phenyl-N-propionyloxy-acetamide 
• 32954-65-7 N,O-diacetylphenylhydroxylamine 
• 3376-33-8 O-methyl acetophenone oxime 

Downstream Products

• 1795-83-1 N-Phenylacetohydroxamic acid 
• 93-26-5 2-methoxyacetanilide 

Relevant academic research and scientific papers

Anionic hetero[3,3] and [3,5][ rearrangements of hydroxylamine derivatives accompanied with N-O bond cleavage

Aromatic and aliphatic N,O-divinylhydroxylamine systems generated in situ from hydroxylamine derivatives smoothly undergo [3,3] rearrangement. The base-catalyzed formation and rearrangement of enolates or dienolates of N-aryl-O-acylhydroxylamines, N,O-dia

Anionic [3,3]-sigmatropic rearrangement of N-phenyl-O-acylhydroxylamines to o-aminophenylcetic acids

N-Phenyl-O-acylhydroxylamines rearrange under basic conditions to afford o-aminophenylacetic acids. The rearrangement can be rationalized in terms of [3,3]-sigmatropic shifts of an enolized N-phenyl-O-acylhydroxyl-amine.

An Electrophilic Aromatic Substitution by N-Methoxyamides via Hypervalen Iodine Intermediates

Treatment of N-methoxyamides with hypervalent iodine compounds generates electron deficient nitrogen species which react intra- or intermolecularly with an aromatic group to give N-aryl-N-methoxyamides in good yields.

Formation of Ketone Diperoxides from Ozonation of O-Methyloximes

The ozonation of the O-methyloximes has been investigated.Besides the corresponding ketones, ketone diperoxides, and N-methoxyamides were produced.The stereochemistry of the ketone diperoxides was studied by the NMR technique.