353252-36-5

Upstream product

• 438225-69-5 U(C₈H₈)(C₄(CH₃)4P)(OPN₃(CH₃)6)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=U(C₈H₈)(C₄(CH₃)4P)(OPN₃(CH₃)6)2B(C₆H₅)4 

Downstream Products

• 438225-69-5 U(C₈H₈)(C₄(CH₃)4P)(OPN₃(CH₃)6)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=U(C₈H₈)(C₄(CH₃)4P)(OPN₃(CH₃)6)2B(C₆H₅)4 

Relevant academic research and scientific papers

The first mixed cyclooctatetraenyl-phospholyl metal complexes. Crystal structure of [U(η-C8H8)(η-C4 Me4P)(BH4)(OC4H8)]

Treatment of [U(COT)(BH4)2(THF)] (1) or [U(COT)(BH4)(THF)2][BPh4] (2) (COT = η-C8H8) with Ktmp (tmp, η-C4Me4P) gave [U(COT)(tmp)(BH4)(THF)] (4),

Synthesis and X-ray crystal structure of [U(η-C8H8)(HMPA)3][BPh4], the first cationic monocyclooctatetraenyl compound of uranium (III), and its neodymium homologue

The title compound was synthesized in 88% yield by reducing the uranium(IV) dication [U(COT)(HMPA)3][BPh4]2 (COT=η-C8H8) with sodium amalgam while the neodymium analogue was prepared by substitution o