353289-47-1

Basic information

• Product Name: [1,1',3',1",3",1"'-Quaterphenyl]-3,3'''-dimethylalcohol
• Synonyms: [1,1',3',1",3",1"'-Quaterphenyl]-3,3'''-dimethylalcohol;[1,3':1',1'':3'',1''':3''',1''''-Quinquephenyl]-3,3''''-dimethyl;1,3,5-Tri(3-hydroxymethylphenyl)benzene;1,3,5-Tri(4-hydroxymethylphenyl)benzene;1,4-Di-(3-hydroxymethylphenyl)-naphthalene;1,4-Di-(4-hydroxymethylphenyl)-naphthalene;2,4,6-Tri(3-hydroxymethylphenyl)-1,3,5-triazine;3-(Anthracen-10-yl)benzyl alcohol
• CAS NO: 353289-47-1
• Molecular Formula: C₂₇H₂₄O₃
• Molecular Weight: 396.48
• Mol File: 353289-47-1.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [1,1',3',1",3",1"'-Quaterphenyl]-3,3'''-dimethylalcohol(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1',3',1",3",1"'-Quaterphenyl]-3,3'''-dimethylalcohol(353289-47-1)
• EPA Substance Registry System: [1,1',3',1",3",1"'-Quaterphenyl]-3,3'''-dimethylalcohol(353289-47-1)

Safety Data

• Hazardous Substances Data: 353289-47-1(Hazardous Substances Data)

Usage

General Description

[1,1',3',1",3",1"'-Quaterphenyl]-3,3'''-dimethylalcohol is a chemical compound composed of a quaterphenyl backbone with two side chains containing methyl and alcohol functional groups. It is commonly used as a building block in the synthesis of organic electronic materials such as light-emitting diodes and organic semiconductors. [1,1',3',1",3",1"'-Quaterphenyl]-3,3'''-dimethylalcohol exhibits high thermal stability and possesses unique optical and electronic properties, making it a valuable component in the development of advanced electronic devices. Its molecular structure and versatile reactivity make it an important intermediate for the production of various functional materials used in optoelectronics and organic electronics. Additionally, its rigid and planar structure makes it an ideal candidate for creating molecular materials with enhanced electronic properties.

Upstream product

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• 117100-41-1 dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate 
• 99768-12-4 4-methoxycarbonylphenylboronic acid 
• 626-39-1 1,3,5-trisbromobenzene 

Downstream Products

• 66449-09-0 1,3,5-tris(p-chloromethylphenyl)benzene 
• 42837-44-5 1,3,5-tris(4-bromomethylphenyl)benzene 

Relevant articles and documents

Synthesis of C3-symmetric tri(alkylamino) guests and their interaction with cyclodextrins

The synthesis of a series of star-shaped C3-symmetric amines and their inclusion complexation properties toward α-, β-, γ-cyclodextrins and their permethylated derivatives has been described. The star molecules comprise of 1, 3, 5-trisubstited benzene core and the points formed by (alkylamino)methyl or 4-((alkylamino)methyl)phenyl groups. The modes of host-guest interaction were studied by UV-Vis spectroscopy, ITC, 1H NMR and 2D-NMR (NOESY). It was found that star molecules containing (tert-butylamino)methyl, (adamantan-1-ylamino)methyl, 4-((isopropylamino)methyl) phenyl, 4-((tert-butylamino)methyl)phenyl and protonated 4-((adamantan-1-ylamino)methyl)phenyl points form strong host-guest complexes with β-cyclodextrin. It was also proved that the largest C3-symmetric guest can form complexes with bcyclodextrin with stoichiometry 3 which is required for construction of dendrimer supramolecular structures. None of the investigated amines forms a strong complex with permethylated cyclodextrins.

Propeller-shaped molecules with giant off-resonance optical nonlinearities

Propeller-shaped molecules based on a triphenylbenzene crux bearing three oligomeric phenylenevinylene branches have been designed; very large first-order hyperpolaris-abilities (up to ∥β∥ = 800 10-30 esu) were obtained while maintaining wide t