353493-98-8Relevant academic research and scientific papers
Catalytic activation of diazo compounds using electron-rich, defined iron complexes for carbene-transfer reactions
Holzwarth, Michael S.,Alt, Isabel,Plietker, Bernd
supporting information; experimental part, p. 5351 - 5354 (2012/07/14)
Carbene transfer: The electron-rich iron complex Bu4N[Fe(CO) 3(NO)] efficiently catalyzes different carbene-transfer reactions. Various diazo compounds can be used. The high stability of the employed iron complexes is demonstrated by the generation of the diazo reagent in situ and a sequential iron-catalyzed allylic sulfenylation/Doyle-Kirmse reaction. Copyright
Ruthenium-catalyzed S-propargylation of thiols enables the rapid synthesis of propargylic sulfides
Kondo, Teruyuki,Kanda, Yusuke,Baba, Atsushi,Fukuda, Kenji,Nakamura, Ayako,Wada, Kenji,Morisaki, Yasuhiro,Mitsudo, Take-aki
, p. 12960 - 12961 (2007/10/03)
A new and highly efficient catalytic system based on CpRuClL2 is proposed for the S-propargylation of thiols by propargylic carbonates under neutral conditions, in which specific requirements inherent to the different reactivities of aliphatic and aromatic thiols are achieved by tuning both the nature of the ancillary ligand L and the experimental conditions. Copyright
