35365-50-5Relevant academic research and scientific papers
Scandium(III) catalysis of transimination reactions. Independent and constitutionally coupled reversible processes
Giuseppone, Nicolas,Schmitt, Jean-Louis,Schwartz, Evan,Lehn, Jean-Marie
, p. 5528 - 5539 (2007/10/03)
Sc(OTf)3 efficiently catalyzes the self-sufficient transimination reaction between various types of C=N bonds in organic solvents, with turnover frequencies up to 3600 h-1 and rate accelerations up to 6 × 105. The mechanism of the crossover reaction in mixtures of amines and imines is studied, comparing parallel individual reactions with coupled equilibria. The intrinsic kinetic parameters for isolated reactions cannot simply be added up when several components are mixed, and the behavior of the system agrees with the presence of a unique mediator that constitutes the core of a network of competing reactions. In mixed systems, every single amine or imine competes for the same central hub, in accordance with their binding affinity for the catalyst metal ion center. More generally, the study extends the basic principles of constitutional dynamic chemistry to interconnected chemical transformations and provides a step toward dynamic systems of increasing complexity.
Five- and six-membered platinacycles derived from phenantryl and anthracenyl imines
Crespo, Margarita,Evangelio, Emilia
, p. 1956 - 1964 (2007/10/03)
The reaction of [Pt2Me4 (μ-SMe2)2] with ligands Me2NCH2CH2NCHAr (2a, Ar=9-phenantryl; 2b, Ar=9-anthracenyl) carried out in acetone at room temperature produced the corresponding
