35377-14-1

Basic information

• Product Name: Bicyclo[2.2.1]heptan-2-one, 3-[(4-chlorophenyl)methylene]-4,7,7-trimethyl-, (1S)-
• CAS NO: 35377-14-1
• Molecular Formula: C17H19ClO
• Molecular Weight: 274.79
• Mol File: 35377-14-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptan-2-one, 3-[(4-chlorophenyl)methylene]-4,7,7-trimethyl-, (1S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptan-2-one, 3-[(4-chlorophenyl)methylene]-4,7,7-trimethyl-, (1S)-(35377-14-1)
• EPA Substance Registry System: Bicyclo[2.2.1]heptan-2-one, 3-[(4-chlorophenyl)methylene]-4,7,7-trimethyl-, (1S)-(35377-14-1)

Safety Data

• Hazardous Substances Data: 35377-14-1(Hazardous Substances Data)

Upstream product

• 10292-98-5 epicamphor 
• 104-88-1 4-chlorobenzaldehyde 

Relevant articles and documents

Determination de la Structure et Configuration Absolue du p-Chlorobenzylidene-2 Epicamphre-(-)-(Z)

C17H19ClO, orthorhombic, P212121, a = 11.587(7), b = 11.234(5), c = 11.021(7) Angstroem, V = 1435 Angstroem3, Z = 4.The structure was solved by direct methods (R = 0.071 for 1126 observed reflexions).The molecule adopts the Z configuration suggested by electronic-spectra, NMR and dipole-moment studies.The conjugated system O=C-C=C is not completely planar but slightly skewed in the sense of a left-handed helix (-3o).The vicinity of the O atom of the carbonyl group and the ortho H atom of the benzene ring (2.03 Angstroem) implies some kind of bond (or interaction) between the orbitals of these two atoms.