354152-92-4Relevant academic research and scientific papers
Highly selective hydrocyanation of butadiene toward 3-pentenenitrile
Bini, Laura,Mueller, Christian,Wilting, Jos,Von Chrzanowski, Lars,Spek, Anthony L.,Vogt, Dieter
, p. 12622 - 12623 (2007)
A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)-complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification. Copyright
Highly efficient nickel-catalyzed 2-methyl-3-butenenitrile isomerization: Applications and mechanistic studies employing the TTP ligand family
Tauchert, Michael E.,Warth, Daniel C. M.,Braun, Sebastian M.,Gruber, Irene,Ziesak, Alexandra,Rominger, Frank,Hofmann, Peter
experimental part, p. 2790 - 2809 (2011/07/29)
A series of sterically and electronically fine-tuned, chelating diphosphine ligands were synthesized. The ligands are analogues of Triptyphos (TTP, 1), all based upon a variably 9,10-two-carbon-bridged 9,10-dihydroanthracene scaffold. These new TTP-type l
