35447-68-8

Basic information

• Product Name: ISOVALERYL BROMIDE
• Synonyms: ISOVALERYL BROMIDE;3-Methylbutanoic acid bromide
• CAS NO: 35447-68-8
• Molecular Formula: C₅H₉BrO
• Molecular Weight: 165.03
• Mol File: 35447-68-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 142.8 °C at 760 mmHg
• Flash Point: 50 °C
• Appearance: /
• Density: 1.355 g/cm³
• Vapor Pressure: 5.51mmHg at 25°C
• Refractive Index: 1.453
• CAS DataBase Reference: ISOVALERYL BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ISOVALERYL BROMIDE(35447-68-8)
• EPA Substance Registry System: ISOVALERYL BROMIDE(35447-68-8)

Safety Data

• Hazardous Substances Data: 35447-68-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C5H9BrO/c1-4(2)3-5(6)7/h4H,3H2,1-2H3

Upstream product

• 503-74-2 3-methylbutyric acid 
• 590-86-3 isovaleraldehyde 

Downstream Products

• 124119-41-1 3,3-bis-(4-isovaleryloxy-phenyl)-phthalide 
• 23566-47-4 5-methyl-1-phenyl-hex-1-yn-3-one 
• 35158-25-9 2-isopropyl-5-methyl-hex-2-enal 
• 590-86-3 isovaleraldehyde 
• 16365-09-6 β-m-Nitro-phenoxy-ethyl-isovalerat 
• 108-64-5 Ethyl isovalerate 
• 5633-85-2 2,7-dimethyl-octane-4,5-dione 
• 150272-54-1 4-chlorophenyl 3-methylbutanoate 
• 103-38-8 benzyl isovalerate 
• 2364-50-3 isovaleranilide 
• 549516-52-1 N,N-dibenzyl-3-methylbutanamide 
• 98379-78-3 3-methyl-N-benzylbutyramide 
• 16204-62-9 1-mesityl-3-methyl-but-1-ene 
• 16204-64-1 2¹-oxy-1.3.5-trimethyl-2-isopentyl-benzene 

Relevant articles and documents

Aerobic oxidative esterification and thioesterification of aldehydes using dibromoisocyanuric acid under mild conditions: No metal catalysts required

A practical direct method for the direct preparation of esters and thioesters from aldehydes is described. Esters and thioesters were synthesized by oxidative esterification and thioesterification via in situ generated acyl bromide intermediates, which were used to react with various alcohols and thiols. The esterification and thioesterification were readily performed in the presence of dibromoisocyanuric acid in dichloromethane, without any metal catalysts and under mild conditions. By using this reaction protocol, various esters and thioesters were prepared in high yields. This effective method offers a promising approach for the facile esterification and thioesterification of aldehydes.