354553-64-3Relevant academic research and scientific papers
Reductive routes to dinuclear d10-d10 palladium(0) complexes and their redistribution equilibria in solution
Reid, Steven M.,Fink, Mark J.
, p. 2959 - 2961 (2001)
The reaction of hydrazine with (dcpe)PdCl2 or (dippe)Pd(OAc)2 leads to high yields of the isolated dinuclear complexes [(μ-dcpe)Pd]2 and [(μ-dippe)Pd]2, respectively. In solution, these dinuclear complexes undergo a monomer-dimer equilibrium with their corresponding 14-electron (P-P)Pd fragments. Solutions containing both [(μ-dcpe)Pd]2 and [(μ-dippe)Pd]2 give near statistical amounts of the novel mixed dimer (μ-dcpe)(μ-dippe)Pd2.
