354576-49-1Relevant academic research and scientific papers
Synthesis and reactions of some optically active epoxides formally derived from tertiary allylic alcohols
Bickley, Jamie F.,Gillmore, Adam T.,Roberts, Stanley M.,Skidmore, John,Steiner, Alexander
, p. 1109 - 1115 (2001)
The epoxyketones 2, 3 and 7-9 reacted with Grignard reagents in a highly stereocontrolled manner to give the epoxyalcohols 20, 4-6 and 11-13 in high yields. The epoxyalcohol 12 underwent a Payne rearrangement on base treatment to give the isomer 15 while
