35477-69-1

Upstream product

• 35478-07-0 benzyl 2-benzoylamino-O⁵,O⁶-isopropylidene-O³-methanesulfonyl-β-D-2-deoxy-glucofuranoside 
• 35478-08-1 (3aR)-4c-benzyloxy-6c-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-phenyl-(3ar,6ac)-3a,4,6,6a-tetrahydro-furo[3,4-d]oxazole 
• 35478-09-2 (R)-1-((3aR)-4c-benzyloxy-2-phenyl-(3ar,6ac)-3a,4,6,6a-tetrahydro-furo[3,4-d]oxazol-6c-yl)-ethane-1,2-diol 

Relevant academic research and scientific papers

Phenyloxazoline derivatives of amino-sugars

The preparation and borohydride reduction of 2,3-dideoxy-5,6-O- isopropylidene-2′-phenyl-D-allofuranoso-[2,3-d]- Δ2′-oxazoline (XXI) are described. The reduction product was a derivative of 2-amino-2-deoxy-D-allitol, indicating that no isomerisation of the sugar system in compound (XXI) had occurred during its formation and reduction. A derivative of muramic acid containing a reduced side chain was synthesised from a phenyloxazoline derivative of 2-amino-2-deoxy-D- glucofuranose. A convenient method for the preparation of the 5,6-carbonate of 1,2-O-isopropylidene-D-glucofuranose and related sugars was also developed.