354796-71-7Relevant academic research and scientific papers
Synthesis and self-assemble nanofibers of tetra phenoxy substituted nickel phthalocyanine
Gao, Junshan,Huang, Guoqing,Du, Xiguang
, p. 1711 - 1713 (2014)
Tetra phenoxy substituted nickel phthalocyanine nanofibers were synthesized in large scale by self-assemble. The FESEM and HRTEM micrographs indicated that the sizes of the fibers are 20-60 nm in width and 0.2-5 μm in length. The formation mechanism of ni
Synthesis, Aggregation Behavior, and Electronic Properties of some Metallophthalocyanines with 2-Isopropyl-5-methylphenoxy Substituents
A?irta?, M. Salih,Karata?, Ceyhun,Gümü?, Sel?uk
, p. 1334 - 1339 (2015)
The aim of this study was to perform facile synthesis of novel phthalocyanines with high solubility. The synthesis and characterization of 2-isopropyl-5-methylphenoxy substituted copper, zinc, nickel, and cobalt phthalocyanines are reported. The compounds
A series of asymmetrical phthalocyanines: Synthesis and near infrared properties
Huang, Guoqing,Li, Jianxi,Cong, Fangdi,Li, Chao,Chu, Xixi,Meng, Yanyan,Du, Guotong,Du, Xiguang
supporting information, p. 4628 - 4639 (2013/06/04)
We report here the preparation of asymmetrical phthalocyanine dimers 1a-3a, which are endowed with novel charge transfer bands at 1,151-1,154 nm and strong NIR luminescences at 840-860 nm and 1,600-1,650 nm. Through H-bonding interaction, 1a-3a are inclined to self-assemble into hexrod nanotubes at the interface of CHCl3 and CH3OH. Our results provide further insights into the interaction in molecular dimers, and suggest that 1a-3a have potential application in magnets and supramolecular architectures.
Synthesis and characterization of several soluble tetraphenoxy-substituted copper and zinc phthalocyanines
Ma, Chunyu,Tian, Dongliang,Hou, Xiaoke,Chang, Yuchun,Cong, Fangdi,Yu, Haifeng,Du, Xiguang,Du, Guotong
, p. 741 - 748 (2007/10/03)
Synthesis of copper and zinc phthalocyanines (Pcs) bearing phenoxy-substituents is described. Precursors required for the preparation of PCS 9-16 are prepared by a nucleophilic aromatic substitution reaction between a sterically hindered phenol derivative and 4-nitrophthalonitrile (1) or 3-nitrophthalonitrile (2). Cyclotetramerization of the resulting precursor phthalonitriles in DMAE or in pentan-1-ol catalyzed by DBU gives desired Pcs, which are well soluble in common organic solvents, such as chloroform and dichloromethane. Each of these Pcs are composed of four constitutional isomers and are characterized by 1H NMR, UV/Vis, IR and mass spectra, as well as elemental analysis, which are consistent with the proposed structures.
