354797-81-2Relevant articles and documents
Stereoselective 2-deoxy-β-O-glycoside synthesis based on remote activation of novel oxathiine donors
Bartolozzi, Alessandra,Capozzi, Giuseppe,Menichetti, Stefano,Nativi, Cristina
, p. 2083 - 2090 (2007/10/03)
Stable glyco-fused 1,4-oxathiine derivatives, prepared by inverse electron-demand Diels-Alder reactions between suitable 1-glycals and 3-thioxopentane-2,4-dione, have been transformed into unusual glycosyl donors which, after "remote activation", react ef
Versatile intermediate for complete α/β stereocontrol in O-glycosidation reactions
Capozzi, Giuseppe,Mannocci, Francesca,Menichetti, Stefano,Nativi, Cristina,Paoletti, Serena
, p. 2291 - 2292 (2007/10/03)
β-O-Glucosides 5, which can be completely converted to the α-anomers in the reaction medium, are obtained as single isomers by glycosidation of readily available donor 1 and are easily transformed into 2-deoxy-β-O-glucosides.