354818-69-2Relevant academic research and scientific papers
Preparation of a rigid bicyclic diphosphine by radical cyclisation
Demay, Stephane,Lotz, Matthias,Polborn, Kurt,Knochel, Paul
, p. 909 - 914 (2001)
Bromodiphosphine oxide 3 was obtained from the selectively protected chiral diol 2 by the double [2,3]-sigmatropic shift of an intermediate phosphinite. The bromophosphine oxide derivative 3 was converted by radical cyclisation into rigid bicyclic diphosp
