35490-70-1Relevant academic research and scientific papers
Base-Promoted Tandem Cyclization for the Synthesis of Benzonitriles by C?C Bond Construction
Zhu, Cheng-Zhi,Wei, Yin,Shi, Min
, p. 808 - 813 (2018)
A facile synthesis of benzonitriles via a base-promoted tandem cyclization reaction of α,β-unsaturated enones having electron-withdrawing group (EWG) and 2-acyl-acrylonitriles was developed. This new synthetic method to access benzonitriles is suitable for a wide range of substrates. A plausible reaction mechanism is proposed on the basis of previous literature and our own investigations. (Figure presented.).
Aldol condensation of β-diketones and β -ketoesters with aldehydes catalyzed by samarium (III) iodide
Bao, Weiliang,Zhang, Yongmin,Wang, Jingang
, p. 3025 - 3028 (2007/10/03)
Catalyzed by SmI3 β-diketones and β-ketoesters condense with aldehydes to give benzylidene substituted β -diketones and β -ketoesters at room temperatures in fair yields. Copyright
