355011-75-5

Basic information

• Product Name: 6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid 9-decynyl ester
• Synonyms: 6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid 9-decynyl ester
• CAS NO: 355011-75-5
• Molecular Weight: 506.801
• Mol File: 355011-75-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid 9-decynyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid 9-decynyl ester(355011-75-5)
• EPA Substance Registry System: 6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid 9-decynyl ester(355011-75-5)

Safety Data

• Hazardous Substances Data: 355011-75-5(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 146830-59-3 6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid methyl ester 
• 4547-43-7 methyl 6-hydroxycaproate 
• 17643-36-6 9-decyn-1-ol 
• 122846-05-3 6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid 

Relevant articles and documents

Catalytic asymmetric synthesis of macrocyclic (E)-allylic alcohols from ω-alkynals via intramolecular 1-alkenylzinc/aldehyde additions

The ω-alkynals yielded macrocyclic (S)-allylic alcohols in a one-pot reaction sequence involving alkyne monohydroboration, boron to zinc transmetalation, and ((+)-DAIB)-catalyzed enantioselective intramolecular ring closure to the aldehyde function. A general study of this macrocyclization methodology is presented with respect to ligand type, size, and nature of the formed rings.