355141-46-7Relevant academic research and scientific papers
Easily Prepared Mono(N,N-dialkylamino)phosphine Palladium(II) Complexes: Structural and Catalytic Evaluation
Adeyinka, Adedapo S.,Holzapfel, Cedric W.,Lamola, Jairus L.,Maumela, Munaka C.,Mmutlane, Edwin M.,Ngodwana, Lonwabo,Shilubana, Joy C.,Vatsha, Banele
, p. 2578 - 2582 (2021/07/06)
The search for efficient, active and universal catalyst systems for transition-metal catalyzed cross-coupling reactions, continues to be of interest to researchers world-wide. Herein, we report two new Pd(II) complexes, effortlessly prepared from N,N-dialkylamino-phosphines for Suzuki-Miyaura cross-coupling reactions. These sufficiently hindered (% VBur=30.0–31.5 %) and electron rich (vCO=1947.41–1946.29 cm?1) aminophosphines formed active catalysts for Suzuki-Miyaura coupling of aryl bromides and chlorides.
Directed ortho metallation chemistry and phosphine synthesis: New ligands for the suzuki-miyaura reaction
Williams, D. Bradley G.,Evans, Stephen J.,De Bod, Henriette,Mokhadinyana, Molise S.,Hughes, Tanya
experimental part, p. 3106 - 3112 (2009/12/28)
We describe the use of the phosphinic amide moiety as an effective directed ortho metallation group for the incorporation of various phosphino groups onto a benzene ring to generate phosphine ligands. These ligands were used to generate active palladium c
