355151-82-5Relevant academic research and scientific papers
Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines
Nishimura, Takahiro,Yasuhara, Yuichi,Hayashi, Tamio
, p. 979 - 981 (2006)
A rhodium complex coordinated with a chiral diene, (R,R)-2,5- diphenylbicyclo[2.2.2]octa-2,5-diene (Ph-bod*), catalyzed the asymmetric addition of dimethylzinc to N-tosylarylimines to give high yields of chiral 1-aryl-1-ethylamines with high enantioselectivity (94-98% ee).
Resolution of ortho- and meta-substituted 1-phenylethylamines with isopropylidene glycerol hydrogen phthalate
Pallavicini, Marco,Valoti, Ermanno,Villa, Luigi,Piccolo, Oreste
, p. 1071 - 1075 (2001)
The hydrogen phthalate of isopropylidene glycerol 1, previously reported as an efficient resolving agent of p-substituted 1-phenylethylamines, was also found to resolve selected o- and m-isomers. In particular, the (S)-enantiomers of 1-(2-methylphenyl)eth
