35572-78-2Relevant articles and documents
ANALYTE DETECTION
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, (2008/12/08)
The present invention relates to sensitive SE(R)RS based methods for detecting analytes such as explosives and drugs, which may be present in a sample at extremely low levels. The methods may be generally carried out in situ employing novel chemistry whic
Change in regioselectivity in the monoreduction of 2,4,6-trinitrotoluene with titanium(III) and vanadium(II) ions in the presence of iron(II) and copper(II) salts
Leibzon,Michalchenko,Leonova,Gultyai
, p. 1203 - 1207 (2007/10/03)
Small additives of iron(II) or copper(II) salts change the regioselectivity of 2,4,6-trinitrotoluene monoreduction with titanium(III) chloride affording predominantly less accessible 2-amino-4,6-dinitrotoluene over 4-amino-2,6-dinitrotoluene (from 25% when the reduction occurs in the absence of the iron and copper salts to 70% in the presence of these salts). A possible mechanism of the process is discussed.
The crystal structures of three primary products from the selective reduction of 2,4,6-trinitrotoluene
Graham, Duncan,Kennedy, Alan R.,McHugh, Callum J.,Smith, W. Ewen,David, William I. F.,Shankland, Kenneth,Shankland, Norman
, p. 161 - 165 (2007/10/03)
The crystal structures of three primary products from the selective reduction of 2,4,6-trinitrotoluene (TNT) have been determined by synchrotron X-ray powder diffraction (2-amino-4,6-dinitrotoluene) and single crystal X-ray diffraction (4-amino-2,6-dinitr
