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9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine is an organic compound characterized by its unique molecular structure, featuring a fluorene core with two methyl groups at the 9,9-positions and a phenyl group attached to the nitrogen atom. 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine is known for its potential applications in organic synthesis and material science.

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  • 355832-04-1 Structure
  • Basic information

    1. Product Name: 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine
    2. Synonyms: 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine;(9,9-DiMethyl-9H-fluoren-2-yl )-phenyl-aMine;2-(Phenylamino)-9,9-dimethylfluorene;N-(9,9-Dimethylfluoren-2-yl)aniline;N-(9,9-DiMethylfluoren-2-yl)aniline/ 2-(PhenylaMino)-9,9-diMethylfluorene;2-Anilino-9,9-dimethylfluorene;9,9-dimethyl-N-phenylfluoren-2-amine
    3. CAS NO:355832-04-1
    4. Molecular Formula: C21H19N
    5. Molecular Weight: 285.38226
    6. EINECS: -0
    7. Product Categories: N/A
    8. Mol File: 355832-04-1.mol
  • Chemical Properties

    1. Melting Point: 99.0 to 103.0 °C
    2. Boiling Point: 448.7±24.0 °C(Predicted)
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: 1.128
    6. Refractive Index: N/A
    7. Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
    8. Solubility: Chloroforom (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
    9. PKA: 0.95±0.40(Predicted)
    10. CAS DataBase Reference: 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine(CAS DataBase Reference)
    11. NIST Chemistry Reference: 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine(355832-04-1)
    12. EPA Substance Registry System: 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine(355832-04-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 355832-04-1(Hazardous Substances Data)

355832-04-1 Usage

Uses

Used in Organic Synthesis:
9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine is used as a synthetic intermediate for the preparation of secondary amines. Its unique structure allows for versatile chemical reactions, making it a valuable building block in the synthesis of various organic compounds.
Used in Material Science:
In the field of material science, 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine can be utilized as a precursor for the development of advanced materials with specific properties. Its incorporation into polymers or other materials can lead to the creation of new materials with improved characteristics, such as enhanced stability, conductivity, or optical properties.
Used in Pharmaceutical Industry:
9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine is used as a key intermediate in the synthesis of pharmaceutical compounds. Its unique structure can be exploited to design and develop new drugs with potential therapeutic applications, contributing to the advancement of medicine and healthcare.
Used in Chemical Research:
In the realm of chemical research, 9,9-diMethyl-N-phenyl-9H-fluoren-2-aMine serves as a valuable compound for studying various chemical reactions and mechanisms. Its reactivity and structural features make it an interesting subject for researchers to explore and understand the underlying principles of organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 355832-04-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,5,8,3 and 2 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 355832-04:
(8*3)+(7*5)+(6*5)+(5*8)+(4*3)+(3*2)+(2*0)+(1*4)=151
151 % 10 = 1
So 355832-04-1 is a valid CAS Registry Number.

355832-04-1Relevant articles and documents

Amine-based compound and organic light emitting diode comprising the same

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Paragraph 0244; 0249-0251, (2021/03/16)

Disclosed are an amine-based compound and an organic light emitting device including the same. The amine-based compound is represented by chemical formula 1A.

Nitrogen-containing compound, organic electroluminescent device, and electronic device

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Paragraph 0111-0115; 0118, (2021/01/24)

The invention provides a nitrogen-containing compound, an organic electroluminescent device and an electronic device, and belongs to the technical field of organic materials. The structure of the nitrogen-containing compound is represented by Chemical Formula 1: wherein X1, X2, Y1, Y2 are the same or different from each other and are each independently a single bond, O, S, N(R3), C(R4R5), Ge(R6R7), Si(R8R9), Se, wherein X1 and Y1 are not single bonds simultaneously and X2 and Y2 are not single bonds simultaneously.

Organic compound, and electronic element and electronic device using same

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Paragraph 0150-0152; 0154, (2021/07/14)

The invention relates to an organic compound. The structure of the organic compound is shown as a formula I. When the organic compound is used as a hole adjustment layer material of an electronic element, driving voltage can be reduced, the luminous efficiency of a device can be improved, and the service life of the device can be prolonged.

COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF

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Paragraph 0103; 0106-0109, (2021/06/22)

In the present invention, provided is a novel compound capable of improving luminance efficiency, stability, and service life of an element, an organic electronic element using the same, and an electronic device thereof. By using the compound of the present invention, high luminance efficiency, low driving voltages, and high heat resistance of the element can be achieved, and color purity and service life of the element can be greatly improved.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICES CONTAINING THE SAME

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Paragraph 0166-0167, (2021/03/03)

To further develop a fluorescent light emitting material so as to obtain a higher element efficiency, a longer lifetime of the device, and more blue emission.SOLUTION: The invention discloses aromatic amine derivative, and an organic electroluminescent device including the same. In a structure, fluorene/silafluorene groups with ortho-substituents are introduced into the aromatic amine derivative, therefore the aromatic amine derivative can be used as light-emitting materials in a light-emitting layer of the organic electroluminescent device. These novel compounds can provide better device performance.SELECTED DRAWING: None

Organic compound, electronic device comprising organic compound and electronic equipment

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Paragraph 0116-0118; 0119-0121, (2021/08/07)

The invention relates to an organic compound, an electronic device comprising the organic compound, and electronic equipment comprising the electronic device. The structural formula of the organic compound is represented by a chemical formula 1, and the organic compound is applied to the electronic device and can significantly improve the performance of the electronic device.

Combined KOH/BEt3Catalyst for Selective Deaminative Hydroboration of Aromatic Carboxamides for Construction of Luminophores

Li, Jinshan,Wang, Jiali,Yang, Jianguo,Yao, Wubing,Zhong, Aiguo

supporting information, p. 8086 - 8090 (2020/11/03)

The selective catalytic C-N bond cleavage of amides into value-added amine products is a desirable but challenging transformation. Molecules containing iminodibenzyl motifs are prevalent in pharmaceutical molecules and functional materials. Here we established a combined KOH/BEt3 catalyst for deaminative hydroboration of acyl-iminodibenzyl derivatives, including nonheterocyclic carboxamides, to the corresponding amines. This novel transition-metal-free methodology was also applied to the construction of Clomipramine and luminophores.

Organic electroluminescent compound, and preparation method and application thereof

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Paragraph 0065-0067; 0069-0071, (2020/09/30)

The invention discloses an organic electroluminescent compound. The structural general formula of the organic electroluminescent compound is represented by chemical formula 1. In the formula 1, A is located at any two adjacent positions on a benzene ring or does not exist on the benzene ring; X is S or O; R1 to R9 are independently selected from a substituted or unsubstituted C1-C30 alkyl group, asubstituted or unsubstituted C6-C30 aryl group, a substituted or unsubstituted heteroaryl group and a substituted or unsubstituted C6-C30 arylamino group respectively, and are connected with adjacentsubstituent groups to form a monocycle or a polycycle; Ar1 and Ar2 are respectively and independently selected from a substituted or unsubstituted C1-C30 alkyl group, a substituted or unsubstituted C6-C30 aryl group and a substituted or unsubstituted heteroaryl group, and are connected with adjacent substituent groups to form a monocycle or a polycycle; and L is a chemical bond, or a substitutedor unsubstituted C6-C30 aryl group. The organic electroluminescent compound is short in synthetic route, simple in process, available in raw materials, low in cost and suitable for industrial production.

Aromatic amine derivative based on spirofluorene and application thereof

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Paragraph 0054-0059, (2020/07/27)

The invention discloses an aromatic amine derivative based on spirofluorene and application of the aromatic amine derivative in an organic light-emitting device, and belongs to the technical field oforganic photoelectric materials and devices thereof. The structure of the aromatic amine derivative is shown as a general formula (I) or a general formula (II), wherein R1 and R2 are independently hydrogen, linear chain or branched chain alkyl containing 1-12 carbons, a benzene ring, and a benzene ring substituted by linear chain or branched chain alkyl containing 1-12 carbons. The organic light-emitting device prepared by adopting the aromatic amine derivative as a hole transport material has the advantages of high brightness, high efficiency and good stability, and the performance of the OLED device can be effectively improved.

Heterocyclic compounds and organic light-emitting diode including the same

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Paragraph 0437; 0444-0449; 0458; 0489-0494, (2020/06/20)

The present invention relates to a novel heterocyclic compound and an organic electroluminescent device including the same as a light emitting material, particularly a heterocyclic compound denoted by chemical formula 1, and an organic electroluminescent device having excellent luminance properties including driving voltage and luminance efficiency.

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