35595-81-4Relevant academic research and scientific papers
REACTION OF CYCLIC KETONES WITH KOH-DMSO
Trofimov, B. A.,Petrova, O. V.,Vasil'tsov, A. M.,Mikhaleva, A. I.
, p. 1450 - 1453 (2007/10/02)
Upon reaction of cycloalkanones with a KOH-DMSO system 2-methylenecycloalkanols are formed, the yield (10-37percent) of which decreases in the series: cyclohexanone > cycloheptanone > cyclooctanone > cyclododecanone
Synthesis of Cyclic Allylic Sulphides (Ring Sizes 5-15) via Phenylthio Participation
Hannaby, Malcolm,Warren, Stuart
, p. 303 - 311 (2007/10/02)
Dehydration of β-phenylthio alcohols occurs with PhS participation unless stereochemistry prevents it.Without PhS participation, mixtures of allylic and vinylic sulphides are formed, but with PhS participation routes to three families of cyclic allylic su
DEHYDRATION OF ALCOHOLS WITH AN ADJACENT PHENYLTHIO (PhS) GROUP
Hannaby, Malcolm,Warren, Stuart
, p. 3133 - 3136 (2007/10/02)
Rings produce particular constraints not experienced by acyclic systems.We have investigated how the change in conformational and steric factors caused by varying the ring size affects a reaction within cyclic systems.
