356055-96-4

Basic information

• Product Name: 3-(4-tert-butyl-phenylsulfanyl)-hexanoic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-benzyl ester
• Synonyms: 3-(4-tert-butyl-phenylsulfanyl)-hexanoic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-benzyl ester
• CAS NO: 356055-96-4
• Molecular Weight: 816.663
• Mol File: 356055-96-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(4-tert-butyl-phenylsulfanyl)-hexanoic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-tert-butyl-phenylsulfanyl)-hexanoic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-benzyl ester(356055-96-4)
• EPA Substance Registry System: 3-(4-tert-butyl-phenylsulfanyl)-hexanoic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyl)-benzyl ester(356055-96-4)

Safety Data

• Hazardous Substances Data: 356055-96-4(Hazardous Substances Data)

Upstream product

• 356055-77-1 (4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)phenyl)methanol 
• 195324-88-0 1-(4'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecane 
• 589-87-7 1,4-bromoiodobenzene 
• 2043-53-0 2-(n-perfluorooctyl)ethyl iodide 
• 27829-72-7 ethyl (E)-hex-2-enoate 
• 2396-68-1 4-t-butylbenzenethiol 
• 356055-83-9 4-(2-perfluorooctyl)ethylbenzyl 2-hexenoate 

Relevant articles and documents

Thiol additions to acrylates by fluorous mixture synthesis: Relative control of elution order in demixing by the fluorous tag and the thiol substituent

All possible combinations of a series of three fluorous benzyl tags and three acrylates have been made. The resulting acrylate esters were combined in groups of three (one of each tag) and the resulting mixtures were reacted with a mixture of four thiols under standard conditions to effect conjugate addition. Analysis of the resulting libraries by fluorous hplc showed a primary separation based on the tag and revealed reliable secondary separations based on the thiol and the acrylate. The primary and secondary separations were used together in a preparative 'mixture of mixtures' experiment in which one of the tagged acrylate mixtures was reacted with a mixture of three thiols. The resulting nine component mixture was demixed by fluorous and reverse phase hplc and then detagged to give all nine final products in pure form.