356060-86-1

Basic information

• Product Name: C₂₉H₃₈O₆Si
• Synonyms: C₂₉H₃₈O₆Si
• CAS NO: 356060-86-1
• Molecular Weight: 510.703
• Mol File: 356060-86-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₉H₃₈O₆Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₉H₃₈O₆Si(356060-86-1)
• EPA Substance Registry System: C₂₉H₃₈O₆Si(356060-86-1)

Safety Data

• Hazardous Substances Data: 356060-86-1(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 21193-75-9 D-galactal 

Downstream Products

• 130323-36-3 3,6-di-O-benzoyl-D-galactal 

Relevant articles and documents

A mild and efficient approach for the regioselective silyl-mediated protection-deprotection of C-4 hydroxyl group on carbohydrates

A regioselective route is reported, which makes the free 4-OH group of hexopyranoses and derivatives easily and rapidly available. This protocol shows high efficiency on intermediates, such as 1a, which contain a TIPS protective group at C-6 and necessarily a benzoyl group at C-4. Treatment of 1a with TBAF cleaves the TIPS protecting group and gives rise to an intramolecular migration of the benzoyl group at C-4 to the less crowded C-6 position.