35638-41-6

Basic information

• Product Name: TetrabutylaMMoniuM perManganate
• Synonyms: TetrabutylaMMoniuM perManganate;tetrabutylazanium,permanganate
• CAS NO: 35638-41-6
• Molecular Formula: C₁₆H₃₆N*MnO₄
• Molecular Weight: 361.399389
• Mol File: 35638-41-6.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: TetrabutylaMMoniuM perManganate(CAS DataBase Reference)
• NIST Chemistry Reference: TetrabutylaMMoniuM perManganate(35638-41-6)
• EPA Substance Registry System: TetrabutylaMMoniuM perManganate(35638-41-6)

Safety Data

• Hazardous Substances Data: 35638-41-6(Hazardous Substances Data)

Usage

General Description

Tetrabutylammonium permanganate is a chemical compound that consists of tetrabutylammonium cations and permanganate anions. It is a powerful oxidizing agent that is commonly used as a reagent in organic chemistry for the oxidation of alcohols and alkenes. Tetrabutylammonium permanganate is a dark purple solid and is stable at room temperature, but can decompose violently at higher temperatures or upon contact with certain organic materials. It is also used in analytical chemistry as a titrant for the determination of various compounds, and in some industrial processes for wastewater treatment and remediation of environmental contaminants. Despite its usefulness in chemical reactions, tetrabutylammonium permanganate should be handled with caution due to its corrosive nature and potential for hazardous decomposition products.

InChI:InChI=1/C16H36N.Mn.4O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;;/h5-16H2,1-4H3;;;;;/q+1;;;;;-1/rC16H36N.MnO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1

Upstream product

• 7722-64-7 potassium permanganate 
• 1643-19-2 tetrabutylammomium bromide 
• 1112-67-0 tetrabutyl-ammonium chloride 

Downstream Products

• 113859-76-0 manganese(picolinate)3(OH₂) 
• 109862-72-8 {Mn₃O(O₂CPh)6(pyridine)2(H₂O)}*0.5CH₃CN 
• 100569-15-1 [Mn(EtOH)4][Mn₂(sal)4(pyr)2] 
• 204141-52-6 MnCl(CH₃C₆H₄COCHCOC₆H₄CH₃)2 
• 228703-82-0 MnCl(CH₃CH₂C₆H₄COCHCOC₆H₄CH₂CH₃)2 
• 228873-05-0 MnCl(C₆H₅COCHCOC₆H₅)2 
• 228703-80-8 MnBr(CH₃C₆H₄COCHCOC₆H₄CH₃)2 
• 228703-83-1 MnBr(CH₃CH₂C₆H₄COCHCOC₆H₄CH₂CH₃)2 
• 228703-79-5 MnBr(C₆H₅COCHCOC₆H₅)2 
• 318497-16-4 N(C₄H₉)4⁽¹⁺⁾*Mn₄O₂(O₂CCH₃)7((CHNHCHNC)CH₂CO₂)2^(1-)=N(C₄H₉)4[Mn₄O₂(O₂CCH₃)7((CHNHCHNC)CH₂CO₂)2] 
• 264216-65-1 Mn(OC(C₆H₅)CHC(C₆H₅)O)2(C₅H₅N)2⁽¹⁺⁾*ClO₄^(1-)=(Mn(C₁₅H₁₁O₂)2(C₅H₅N)2)ClO₄ 

Relevant articles and documents

Rapid room-Temperature synthesis of ultrasmall cubic Mg-Mn spinel cathode materials for rechargeable Mg-ion batteries

Reducing the particle size of cathode materials is effective to improve the rate capability of Mg-ion batteries. In this study, ultrasmall cubic Mg-Mn spinel oxide nanoparticles approximately 5 nm in size were successfully synthesized via an alcohol reduction process within 30 min at room temperature. Though the particles aggregated to form large secondary particles, the aggregation could be suppressed by covering the particles with graphene. The composite exhibited a specific capacity of 230 mA h g-1, and could be cycled more than 100 times without any large capacity loss even at a moderate current density with the Mg(ClO4)2/CH3CN electrolyte.

Synthesis, structure and magnetic properties of oxo-centered trinuclear manganese complex [Mn3O(O2CC3H7)6(C 5H5N)3]·ClO4

The reaction of N-n-Bu4MnO4 with Mn(OAc)2·4H2O, pyridine and butyric acid in absolute EtOH leads to the high-yield formation of the oxo-centered trinuclear Mn complex, [Mn3O(O2CC3H7)6(C 5H5N)3]·ClO4. The complex crystallizes in orthorhombic, space group Pna21 with a=19.588(7), b=20.194(6), c=12.491(5) A. Variable temperature solid state magnetic susceptibility study shows that the antiferromagnetic exchange interaction is weak, and the exchange integral J=-12.36 cm-1.

A synthetic model for the oxygen-evolving complex in Sr2+- containing photosystem II

A novel heterometallic MnSr complex containing the Mn3SrO 4 cuboidal moiety and all types of μ-O2- moieties observed in the oxygen-evolving complex (OEC) in Sr2+-containing photosystem II (PSII) has been synthesized and characterized, which provides a new synthetic model of the OEC.