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Trioctylmethylammonium iodide, also known as TOMA iodide, is a quaternary ammonium salt that is widely recognized for its role as a phase transfer catalyst in a variety of organic reactions. This white crystalline powder is soluble in both polar organic solvents and water, and it is particularly noted for its capacity to transfer anions from an aqueous phase to an organic phase, which is instrumental in the extraction and purification of a range of organic compounds. TOMA iodide's unique properties have also placed it under investigation for potential applications in the realms of organic electronics and optoelectronics.

35675-86-6

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35675-86-6 Usage

Uses

Used in Organic Synthesis:
TOMA iodide is utilized as a phase transfer catalyst for facilitating various organic reactions. Its ability to transfer anions between phases enhances the efficiency and selectivity of these reactions, making it a valuable tool in the synthesis of pharmaceuticals, agrochemicals, and specialty chemicals.
Used in Pharmaceutical Industry:
In the pharmaceutical sector, TOMA iodide is employed as a catalyst in the synthesis of various drugs. Its role in phase transfer catalysis aids in the production of complex organic molecules that are often the active ingredients in medications.
Used in Agrochemical Industry:
Similarly, in the agrochemical industry, TOMA iodide serves as a phase transfer catalyst, enabling the synthesis of compounds used in pesticides and other agricultural chemicals, thereby contributing to the development of more effective and targeted products for crop protection.
Used in Specialty Chemicals Production:
TOMA iodide is also used in the production of specialty chemicals, where its catalytic properties are leveraged to create specific compounds with unique applications in various industries.
Used in Organic Electronics and Optoelectronics:
TOMA iodide is being studied for its potential applications in the field of organic electronics and optoelectronics. Its unique properties make it a candidate for use in the development of new materials and devices with enhanced performance characteristics in these high-tech fields.

Check Digit Verification of cas no

The CAS Registry Mumber 35675-86-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,5,6,7 and 5 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 35675-86:
(7*3)+(6*5)+(5*6)+(4*7)+(3*5)+(2*8)+(1*6)=146
146 % 10 = 6
So 35675-86-6 is a valid CAS Registry Number.
InChI:InChI=1/C25H54N.HI/c1-5-8-11-14-17-20-23-26(4,24-21-18-15-12-9-6-2)25-22-19-16-13-10-7-3;/h5-25H2,1-4H3;1H/q+1;/p-1

35675-86-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl(trioctyl)azanium,iodide

1.2 Other means of identification

Product number -
Other names EINECS 252-672-1

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:35675-86-6 SDS

35675-86-6Downstream Products

35675-86-6Relevant academic research and scientific papers

Reducing the competition: A dual-purpose ionic liquid for the extraction of gallium from Iron Chloride solutions

Kinsman, Luke M. M.,Love, Jason B.,Morrison, Carole A.,Ngwenya, Bryne T.

, (2020)

The separation of gallium from iron by solvent extraction from chloride media is challenging because the anionic chloridometalates, FeCl4? and GaCl4?, display similar chemical properties. However, we report here that the selective separation of gallium from iron in HCl solution can be achieved using the dual-purpose ionic liquid methyltrioctylammonium iodide in a solvent extraction process. In this case, the reduction of Fe3+ to Fe2+ by the iodide counterion was found to inhibit Fe transport, facilitating quantitative Ga extraction by the ionic liquid with minimal Fe extraction from 2 M HCl.

Extraction of zinc and copper with acetylenic quaternary ammonium salts

Andreev,Tunina,Remizova

, p. 672 - 678 (2005)

Extraction of zinc(II) and copper(II) from HCl solutions with solutions of mono- and dialkynyl-substituted quaternary ammonium halides in chloroform and toluene is more efficient than the extraction with saturated quaternary ammonium salts and occurs by different mechanism. The dependences of the metal distribution factors on the HCl concentration have two maxima whose positions (absolute and relative) and relative intensities depend on the particular extractant, metal, and diluent. 2005 Pleiades Publishing, Inc.

Separation of precious metals by split-anion extraction using water-saturated ionic liquids

Nguyen, Viet Tu,Rian?, Sofiá,Binnemans, Koen

, p. 8375 - 8388 (2020/12/29)

A split-anion solvent extraction process was developed for the separation of precious metal ions Au(iii), Pt(iv), Pd(ii) and Rh(iii) from aqueous chloride media using water-saturated ionic liquids. The metal extraction and stripping behavior of the chloride form [A336][Cl], bromide form [A336][Br] and the iodide form [A336][I] of the quaternary ammonium ionic liquid Aliquat 336 were compared. The three ionic liquids extracted Au(iii), Pd(ii) and Pt(iv) quantitatively in most cases, whereas the co-extraction of Rh(iii) was strongly dependent on the acidity and the chloride concentration. Among the studied ionic liquids, [A336][I] achieved the highest separation factors between Pd(ii)/Rh(iii), Pt(iv)/Rh(iii), and Au(iii)/Rh(iii) at 6 mol L-1 Cl-. Additionally, the selective stripping of the individual metal ions Pd(ii), Au(iii), and Pt(iv) was only possible from loaded [A336][I] using ammonia solution (NH4OH), sodium thiosulfate (Na2S2O3), and thiourea ((NH2)2CS), respectively. A closed-loop flow sheet was designed for the recovery of the precious metals from chloride media using split-anion extraction with [A336][I]. The integrated process was demonstrated to be suitable for the purification of Rh(iii), Pt(iv) and Pd(ii) from a complex metal feed such as the leachate of spent automotive catalysts. The ionic liquid-based split-anion extraction process is simple, selective and effective for the sustainable separation of the precious metals, using only one green extractant [A336][I], which can be regenerated for consecutive extraction-stripping cycles.

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