356786-39-5Relevant academic research and scientific papers
First synthesis of cationic [(η6-arene)Mn(CO)3] complexes substituted by resonance electron withdrawing groups
Auffrant, Audrey,Prim, Damien,Rose-Munch, Fran?oise,Rose, Eric,Vaissermann, Jacqueline
, p. 3214 - 3216 (2001)
An unprecedented class of cationic [(η6-RCO-arene)Mn(CO)3] complexes bearing resonance electron withdrawing groups have been synthesized by a high-yield two-step methodology starting from the neutral (η5-1-chlorocyclohexadienyl)Mn(CO)3 complex, employing a facile and selective transition-metal-catalyzed carbonylation followed by rearomatization. Definitive spectroscopic details of the novel [(η6-RCO-arene)Mn(CO)3]+ products are discussed, and in one case (R = PhO), the structure has been confirmed by X-ray crystallography.
Palladium-catalyzed chloride substitution of η5-(Chlorocyclohexadienyl)Mn(CO)3 complexes: An access to novel η6-(Arene)Mn(CO)3+ cations
Auffrant, Audrey,Prim, Damien,Rose-Munch, Francoise,Rose, Eric,Schouteeten, Stephanie,Vaissermann, Jacqueline
, p. 1898 - 1913 (2008/10/08)
Functionalization of η5-(chlorocyclohexadienyl)Mn(CO)3 complexes was achieved by palladium-catalyzed reactions using Pd2(dba)3 in the presence of AsPh3. Arylation, carbonylation, and substitution by a
