35679-01-7

Basic information

• Product Name: Rhodium, dicarbonylchloro(triphenylphosphine)-
• CAS NO: 35679-01-7
• Molecular Formula: C20H15ClO2PRh
• Molecular Weight: 456.67
• Mol File: 35679-01-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Rhodium, dicarbonylchloro(triphenylphosphine)-(CAS DataBase Reference)
• NIST Chemistry Reference: Rhodium, dicarbonylchloro(triphenylphosphine)-(35679-01-7)
• EPA Substance Registry System: Rhodium, dicarbonylchloro(triphenylphosphine)-(35679-01-7)

Safety Data

• Hazardous Substances Data: 35679-01-7(Hazardous Substances Data)

Upstream product

• 14694-95-2 Wilkinson's catalyst 
• 201230-82-2 carbon monoxide 

Downstream Products

• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 148906-52-9 (Ph₃P)2Rh(I)(CO)2Cl 

Relevant articles and documents

Formation of anionic carbonylrhodium complexes from Wilkinson's complexes under conditions of hydroformylation of formaldehyde

The compositions and the dynamics of transformations of carbonylrhodium complexes formed from Wilkinson's complexes, RhCl(PPh3)3, dissolved in mesitylene-N,N-dimethylacetamide (DMAA) mixtures in which the DMAA concentration varied from 0 to 100 percent, in an atmosphere of synthesis gas (pCO+H2 = 6 MPa, T = 373 K) were investigated in situ by IR spectroscopy.The anion complexes, - (x = 1, 2; y = 1, 0) and -, which are the centers of formaldehyde hydrofomylation, are produced in noticeable quantities when 100 percent DMAA is used as a solvent.Separate steps of the formation of anionic complexes from RhCl(PPh3)3 have been identified.Under the conditions of hydroformylation of formaldehyde, CH2O participates in the formation of the anionic complexes along with DMAA.