35682-31-6Relevant academic research and scientific papers
Radical and heck cyclizations of Diastereomeric o -haloanilide atropisomers
Guthrie, David B.,Geib, Steven J.,Curran, Dennis P.
, p. 115 - 122 (2011/03/16)
The outcomes of radical cyclizations and Heck reactions of N-(cyclohex-2-enyl)-N-(2-iodophenyl)acetamides depend critically on the configurations of the chiral axis and the stereocenter. In substrates without an ortho-methyl group, the diastereomeric prec
Kinetic resolutions of lndolines by a nonenzymatic acylation catalyst
Arp, Forrest O.,Fu, Gregory C.
, p. 14264 - 14265 (2008/03/13)
The first method for the kinetic resolution of indolines through catalytic N-acylation is described. To improve the selectivity factor, new planar-chiral PPY-derived catalysts were synthesized, wherein the chiral environment was systematically modified. This work provides a rare example of a nonenzyme-based acylation catalyst for the kinetic resolution of amines. Copyright
