357282-69-0

Upstream product

• 71979-00-5 benzyl 4-O-acetyl-2,3-dideoxy-β-D-glycero-pent-2-enopyranoside 
• 100-51-6 benzyl alcohol 

Downstream Products

• 405145-94-0 benzyl β-L-4-azido-2,3,4-trideoxypent-2-enoglyceropyranoside 
• 405145-97-3 benzyl β-L-4-amino-2,3,4-trideoxypent-2-enoglyceropyranoside 
• 405145-91-7 benzyl β-D-4-O-methanesulfonyl-2,3-dideoxypent-2-enoglyceropyranoside 

Relevant academic research and scientific papers

Steric constraints against [3,3]-sigmatropic rearrangement of allylic azides. A convenient approach to β-L-4-aminopent-2-enoglyceropyranosides

Starting from alkyl α-D-4-0-methanesulphonylpent-2-enoglyceropyranosides 13a-c, nucleophilic substitution carried out with polymer-supported azide ion led to regioisomeric mixtures of the azides 14a-c and 15a-c. An analogous result, due to a [3,3]-sigmatr