357407-81-9Relevant academic research and scientific papers
Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: proof of concept.
Kobayashi,Hayashi,Tan,Kishi
, p. 2245 - 2248 (2007/10/03)
[structure: see text] An NMR database approach in a chiral solvent allows us to predict both relative and absolute stereochemistry of an unknown compound without degradation and/or derivatization. N,alpha-Dimethylbenzylamine (DMBA) is a suitable solvent for this purpose. Using the C.5-C.10 portion of oasomycin A, the feasibility and reliability of this approach is demonstrated.
Direct observation of deuterium migration in crystalline-state reaction by single-crystal neutron diffraction. II. 3-1 photoisomerization of a cobaloxime complex
Ohhara, Takashi,Harada, Jun,Ohashi, Yuji,Tanaka, Ichiro,Kumazawa, Shintaro,Niimura, Nobuo
, p. 245 - 253 (2007/10/03)
Single crystal neutron diffraction analysis of photo-exposed (3-cyanopropyl-d2 α,α)-[(R)-1-phenylethylamine-d 11]bis(dimethylglyoximato-d14)cobalt(III) was carried out in order to clarify the mechanism of the cr
