35757-92-7

Upstream product

• 66946-86-9 2,5-dichlorothiophenium-1-bis(methoxycarbonyl)methylide 
• 62-53-3 aniline 
• 868-26-8 dimethyl 2-bromomalonate 

Downstream Products

• 3298-40-6 mesoxalate de methyle 
• 2401-98-1 dimethyl di(phenylamino)malonate 
• 65390-51-4 dimethyl 2,2-dihydroxymalonate 
• 39126-23-3 anilino-malonic acid diamide 
• 39126-37-9 anilino-malonic acid 
• 62851-38-1 dimethyl (p-bromophenylamino)malonate 
• 19038-40-5 5-oxo-1,3-diphenyl-pyrrolidine-2,2-dicarboxylic acid dimethyl ester 
• 131843-76-0 Dimethyl (2-Chloro-N-phenylacetamido)malonate 
• 31827-04-0 methyl 3-hydroxy-1H-indole-2-carboxylate 
• 131843-87-3 Methyl 3,4-Dihydro-5-methoxy-4-oxo-3-phenyl-1,2,4-triazino<1,6-a>indole-2-carboxylate 
• 131843-85-1 Methyl 1,4,5,6-Tetrahydro-1-<2-(methoxycarbonyl)phenyl>-5-oxo-4-phenyl-1,2,4-triazine-3-carboxylate 
• 131843-82-8 Methyl 7-Chloro-3,4-dihydro-4-oxo-3,5-diphenyl-1,2,4-triazino<1,6-a>indole-2-carboxylate 
• 131843-80-6 Methyl 1-(2-Benzoyl-4-chlorophenyl)-1,4,5,6-tetrahydro-5-oxo-4-phenyl-1,2,4-triazine-3-carboxylate 
• 131877-90-2 Dimethyl 2-(2-Chloro-N-phenylacetamido)-2-<2-(methoxycarbonyl)phenylazo>malonate 

Relevant academic research and scientific papers

Bis(methoxycarbonyl)carbene Insertion into N-H Bonds: A Facile Route to N-Substituted Aminomalonic Esters

Bis(methoxycarbonyl)carbene, generated by the cooper(II)-catalyzed fragmentation of 2,5-dichlorothiophenium-1-bis(methoxycarbonyl)methylide (3) undergoes rapid and efficient insertion into the N-H bonds of primary and secondary amines to generate N-substi

ARYLIMINOMALONIC ESTERS

The condensation of nitrosobenzene with malonis esters is the best method for the production of dialkyl phenyliminomalonates, whereas the thermolysis of symmetrical and unsymmetrical di(arylamino)malonic esters is a good method for the synthesis of substituted dialkyl aryliminomalonates.