35758-76-0

Basic information

• Product Name: Benzenamine, N-hydroxy-2-methoxy-
• CAS NO: 35758-76-0
• Molecular Formula: C7H9NO2
• Molecular Weight: 139.154
• Mol File: 35758-76-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-hydroxy-2-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-hydroxy-2-methoxy-(35758-76-0)
• EPA Substance Registry System: Benzenamine, N-hydroxy-2-methoxy-(35758-76-0)

Safety Data

• Hazardous Substances Data: 35758-76-0(Hazardous Substances Data)

Upstream product

• 91-23-6 2-Nitroanisole 
• 64-17-5 ethanol 
• 71-43-2 benzene 

Downstream Products

• 13620-57-0 (Z)-1,2-bis(2-methoxyphenyl)diazene 1-oxide 
• 13620-57-0 2.2'-dimethoxy-seqtrans-azoxybenzene 
• 127089-94-5 N-Hydroxy-N-(2-methoxy-phenyl)-formamide 
• 582319-20-8 methyl 7-methoxy-1H-indole-3-carboxylate 
• 90-04-0 2-methoxy-phenylamine 
• 82344-34-1 N-benzoyl-2-chloro-6-methoxyaniline 
• 82344-35-2 N-aceto-2-chloro-6-methoxyaniline 
• 82344-33-0 N-hydroxy-N-(2-methoxyphenyl)acetamide 
• 17075-26-2 2-nitrosoanisole 

Relevant articles and documents

Electrochemically Tuned Oxidative [4+2] Annulation and Dioxygenation of Olefins with Hydroxamic Acids

This work represents the first [4+2] annulation of hydroxamic acids with olefins for the synthesis of benzo[c][1,2]oxazines scaffold via anode-selective electrochemical oxidation. This protocol features mild conditions, is oxidant free, shows high regioselectivity and stereoselectivity, broad substrate scope of both alkenes and hydroxamic acids, and is compatible with terpenes, peptides, and steroids. Significantly, the dioxygenation of olefins employing hydroxamic acid is also successfully achieved by switching the anode material under the same reaction conditions. The study not only reveals a new reactivity of hydroxamic acids and its first application in electrosynthesis but also provides a successful example of anode material-tuned product selectivity.

Synthesis of meta-substituted anilines via copper-catalyzed [1,3]-methoxy rearrangement

meta-Substituted anilines were efficiently synthesized via copper-catalyzed [1,3]-methoxy rearrangement of N-methoxyanilines followed by Michael addition of nucleophiles to the in situ generated ortho-quinol imine. The present reaction exhibits excellent

Rhodium(III)-catalyzed internal oxidative coupling of N-hydroxyanilides with alkenes via C-H activation

Abstract Described herein is an efficient new method for ortho-olefination of anilides in the presence of AgSbF6 and NaOAc via rhodium(III)-catalyzed internal oxidative C-H bond activation based on hydroxyl as directing and oxidative group. A range of alkenes and functional groups on acetanilides is supported and a possible mechanism is proposed according to the experimental results.