357615-34-0

Basic information

• Product Name: ethyl 3-(tert-butyldiphenylsilyloxy)-4-oxobutyrate
• Synonyms: ethyl 3-(tert-butyldiphenylsilyloxy)-4-oxobutyrate
• CAS NO: 357615-34-0
• Molecular Weight: 384.547
• Mol File: 357615-34-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 3-(tert-butyldiphenylsilyloxy)-4-oxobutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-(tert-butyldiphenylsilyloxy)-4-oxobutyrate(357615-34-0)
• EPA Substance Registry System: ethyl 3-(tert-butyldiphenylsilyloxy)-4-oxobutyrate(357615-34-0)

Safety Data

• Hazardous Substances Data: 357615-34-0(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 371228-83-0 3-(tert-butyldiphenylsilyloxy)pent-4-eneoic acid ethyl ester 
• 38996-01-9 ethyl 3-hydroxypent-4-enoate 

Relevant articles and documents

A concise synthesis of turneforcidine via a metalloiminium ion cyclization terminated by the 2-(methylthio)-3-(trimethylsilyl)-1-propenyl moiety.

A concise synthetic route to racemic turneforcidine (1) is described that relies on the stereocontrolled cyclization of the 2-(methylthio)-3-(trimethylsilyl)-1-propenyl bearing imine 5 in the presence of TiCl(4). Reaction: see text.