35779-15-8Relevant academic research and scientific papers
THE THIOLATE ANION AS A NUCLEOPHILE. PART XIII. REACTIONS OF SOME TIN(II) AROMATIC THIOLATES
Hynes, Rosemary C.,Peach, Michael E.
, p. 129 - 134 (2007/10/02)
The reactions of tin(II) benzenethiolate and p-toluenethiolate with various fluoroaromatics in DMF have been studied.Replacement of some of the aromatic fluorines by the thiolate group was observed.The tin(II) aromatic thiolates are comparable in reactivity in these reactions with lead(II) benzenethiolate.All new compound have been characterized by elemental analysis, and NMR (H-1 and F-19) and mass spectroscopy.
POSSIBILITY OF USING ANTIMONY PENTAFLUORIDE INTERCALATED IN GRAPHITE AS CATALYSTS FOR REACTIONS OF THE FRIEDEL-CRAFTS TYPE
Gurin, G. G.,Avramenko, A. A.,Nikonorov, Yu. I.,Yakobson, G. G.
, p. 1340 - 1345 (2007/10/02)
Antimony pentafluoride intercalated in graphite, produced by the reaction of gaseous antimony pentafluoride with powdered graphite in a flow-type system at 140-160 deg C, exhibits the characteristics of liquid antimony pentafluoride in the temperature range of 50-100 deg C and can be used as a catalyst for various processes of the Friedel-Crafts type.The alkylation (by 1-bromooctane, cyclohexene, cyclopentene, and acylation by capryloyl, benzoyl, and perfluorobutyryl chlorides) of benzene were realized.The oxidative characteristics of antimony pentafluoride were used for the generation of the polyatomic doubly charged sulfur cation and electrophilic reagents from polyfluorodiaryl disulfide, lead thiocyanate, and mercuric oxide and their introduction into reaction with benzene.
