358-03-2Relevant academic research and scientific papers
Transformation of Carbonyl Compounds into gem-Difluoro Compounds with Dibromodifluoromethane/Zinc Reagent
Hu, Chang-Ming,Qing, Feng-Ling,Shen, Cun-Xi
, p. 335 - 338 (2007/10/02)
Reaction of carbonyl compounds with dibromodifluoromethane/zinc gives the gem-difluoro compounds (12 examples).It seems to be that the reaction involves the generation of difluorocarbene by reaction of dibromodifluoromethane with zinc, followed by product
REACTIONS OF ALIPHATIC KETONES WITH SULFUR TETRAFLUORIDE AND HF IN THE PRESENCE OF SULFUR MONOCHLORIDE
Muratov, N.N.,Mohamed, Nagib Muhtar,Kunshenko, B.V.,Burmakov, A.I.,Alekseeva, L.A.,Yagupol'skii, L.M.
, p. 1292 - 1296 (2007/10/02)
Aliphatic ketones react with SF4 and anhydrous hydrogen fluoride in the presence of catalytic amounts of S2Cl2 to give polyfluorinated sulfides and disulfides.The reactions occur via intermediate alkene derivatives.
