35813-95-7Relevant academic research and scientific papers
Cascade Cyclizations of α,β-Unsaturated Thioesters: Additional Examples
Ahlemeyer, Nicholas A.,Straub, Matthew R.,Leace, David M.,Matz, Benjamin A.,Birman, Vladimir B.
, p. 1191 - 1197 (2021)
Several additional examples of cascade cyclizations of α,β-unsaturated thioesters proceeding are reported, which proceed via two distinct mechanistic pathways: enantioselective acyl transfer promoted by amidine-based catalysts (ABCs) and a racemic chain mechanism mediated by a thiolate nucleophile.
