35828-06-9

Basic information

• Product Name: [Ru(η-diphenylacetylene)(CO)2(triphenylphosphine)2]
• CAS NO: 35828-06-9
• Molecular Weight: 859.906
• Mol File: 35828-06-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Ru(η-diphenylacetylene)(CO)2(triphenylphosphine)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(η-diphenylacetylene)(CO)2(triphenylphosphine)2](35828-06-9)
• EPA Substance Registry System: [Ru(η-diphenylacetylene)(CO)2(triphenylphosphine)2](35828-06-9)

Safety Data

• Hazardous Substances Data: 35828-06-9(Hazardous Substances Data)

Upstream product

• 35880-54-7 {ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)} 
• 501-65-5 diphenyl acetylene 
• 871128-13-1 [RuH(C₂C₂H)(CO)2(triphenylphosphine)2] 

Downstream Products

• 14741-36-7 [Ru(CO)3(triphenylphosphine)2] 
• 809241-31-4 [Ru(CO)(triphenylphosphine)2(η4-2-phenyl-1-indenone)]* dichloromethane 
• 35880-54-7 {ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)} 
• 94658-86-3 (tetraphenylcyclobutadienone)Ru(CO)2(PPh₃) 
• 809241-30-3 [Ru(CO)(triphenylphosphine)2(η4-2-phenyl-1-indenone)] 

Relevant articles and documents

A bimetallic complex spanned by the CeH ligand: Synthesis of [Cl(CO) 2L2RuC=CCH=C=RuL2(η-C5H 5)]PF6 (L = PPh3)

The synthesis of the first example of a bime-tallic complex spanned by the C4H alkynylvinylidene ligand, [Cl(CO)2L 2RuC≡CCH=C-RuL2(η-C5H 5]PF6 (L = PPh3), is reported: the reaction of [Ru(CO)2L3] with butadiyne provides [RuH(C≡CC≡ CH)(CO)2L2], which is converted to the chloro derivative [RuCl(C≡CC≡CH)-(CO)2L2] by N-chlorosuccinimide. Subsequent treatment with [Ru(thf)L2(η- C5H5)]PF6 provides [Cl(CO)2L 2RuC≡ CCH=C=RuL2(η-C5H 5)]PF6, deprotonation of which affords [Cl(CO) 2L2RuC≡CC≡CRuL2(η-C 5H5)].