358616-29-2Relevant academic research and scientific papers
Experimental and theoretical characterization of H2OOO +
Zhou, Mingfei,Zeng, Aihua,Wang, Yun,Kong, Qingyu,Wang, Zhi-Xiang,Van Rague Schleyer, Paul
, p. 11512 - 11513 (2003)
This report presents the preparation and characterization of H2OOO+, an important intermediate in water-oxygen chemistry. The H2OOO+ cation was produced by co-deposition of H2O/Ar with radio frequency discharged O2/Ar at 4 K and was identified by four fundamental infrared absorptions. Quantum chemical calculations indicate a doublet ground state with a H2O-O2hemi-bonded Cs structure. Copyright
