358751-08-3Relevant articles and documents
C-X (X=Br, I) bond-tolerant aerobic oxidative cross-coupling: A strategy to selectively construct β-aryl ketones and aldehydes
Chen, Mao,Wang, Jie,Chai, Ziyi,You, Cai,Lei, Aiwen
supporting information; experimental part, p. 341 - 346 (2012/05/04)
Using moelcular oxygen as the terminal oxidant, various aryl halide-containing β-aryl ketones and aldehydes can be synthesized directly from readily available allyic alcohols and boronic acids via palladium-catalyzed oxidative cross-coupling reactions. The dual roles of copper, including electron-carrier and Lewis acid functions, are supposed to be critical for the high reactivity and selectivity of this aerobic oxidative coupling transformation. Copyright
Double arylation of allyl alcohol via a one-pot heck arylation- isomerization-acylation cascade
Colbon, Paul,Ruan, Jiwu,Purdie, Mark,Mulholland, Keith,Xiao, Jianliang
supporting information; experimental part, p. 5456 - 5459 (2011/12/05)
A one-pot, two-step catalytic protocol has been developed. A regioselective Heck coupling between aryl bromides and allyl alcohol leads to the generation of arylated allyl alcohols that in situ isomerize to give aldehydes, which then undergo an acylation reaction with a second aryl bromide. A variety of aryl bromides can be employed in both the initial Heck reaction and the acylation, providing easy access to a wide variety of substituted dihydrochalcones.
Synthesis of xanthenes, Indanes, and tetrahydronaphthalenes via intramolecular phenyl-carbonyl coupling reactions
Kuo, Chih-Wei,Fang, Jim-Min
, p. 877 - 892 (2007/10/03)
Benzaldehydes and acetophenones bearing tethered carbonyl chains underwent the intramolecular phenyl-carbonyl coupling reactions, by mediation of samarium diiodide and hexamethylphosphoramide, to afford the xanthenes and fused benzocarbocyclic compounds c
