358970-67-9Relevant academic research and scientific papers
Iodo bis bistrimethylsilylamido lanthanides
Collin, Jacqueline,Giuseppone, Nicolas,Jaber, Nada,Domingos, Angela,Maria, Leonor,Santos, Isabel
, p. 271 - 274 (2001)
Reactions of lanthanide triiodides with potassium bistrimethylsilyl amide have been investigated. For lanthanum, recrystallisation from THF-toluene led to monocrystals of the dimeric bisamide [La(μ-I){N(TMS)2}2(THF)]2. We have shown that samarium diiodide and lanthanide triiodides are efficient for lanthanum and samarium reactions, a mixture of tris amides and iodo bisamides is obtained, while only the latter compound is obtained for ytterbium.
