Cas 358971-05-8,Ru2(CO)4(H)2(P(C(CH3)3)2)((C6H5)2PCH2P(C6H5)2)(1+)*BF4(1-)=[Ru2(CO)4(H)2(P(C4H9)2)((C6H5)2PCH2P(C6H5)2)]BF4

358971-05-8

Post Buying Request

Basic information

Product Name: Ru₂(CO)4(H)2(P(C(CH₃)3)2)((C₆H₅)2PCH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[Ru₂(CO)4(H)2(P(C₄H₉)2)((C₆H₅)2PCH₂P(C₆H₅)2)]BF₄
Synonyms:
CAS NO:358971-05-8
Molecular Formula:
Molecular Weight: 932.604
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Ru₂(CO)4(H)2(P(C(CH₃)3)2)((C₆H₅)2PCH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[Ru₂(CO)4(H)2(P(C₄H₉)2)((C₆H₅)2PCH₂P(C₆H₅)2)]BF₄(CAS DataBase Reference)
NIST Chemistry Reference: Ru₂(CO)4(H)2(P(C(CH₃)3)2)((C₆H₅)2PCH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[Ru₂(CO)4(H)2(P(C₄H₉)2)((C₆H₅)2PCH₂P(C₆H₅)2)]BF₄(358971-05-8)
EPA Substance Registry System: Ru₂(CO)4(H)2(P(C(CH₃)3)2)((C₆H₅)2PCH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[Ru₂(CO)4(H)2(P(C₄H₉)2)((C₆H₅)2PCH₂P(C₆H₅)2)]BF₄(358971-05-8)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 358971-05-8(Hazardous Substances Data)

Suppliers
Usage
Upstream product
Downstream Products
Article

358971-05-8 Suppliers

Recommended suppliers

358971-05-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 358971-05-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,8,9,7 and 1 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 358971-05:
(8*3)+(7*5)+(6*8)+(5*9)+(4*7)+(3*1)+(2*0)+(1*5)=188
188 % 10 = 8
So 358971-05-8 is a valid CAS Registry Number.

358971-05-8Upstream product

358971-05-8Downstream Products

358971-05-8Relevant academic research and scientific papers

Synthesis and crystal structure of [Ru2(CO)4(μ-H) (μ-NO)(μ-PtBu2)(μ-PPh2CH2PPh 2)]BF4

Boettcher, Hans-Christian,Mayer, Tobias

, p. 1884 - 1888 (2012/01/12)

The reaction of the coordinatively unsaturated complex [Ru 2(CO)4(μ-H)(μ-PtBu2)(μ-dppm)] (1, dppm = Ph2PCH2PPh2)] with the nitrosonium ion was revisited. Even by variation of the reaction conditions, the reaction afforded in each case not the sole addition product [Ru2(CO) 4(μ-NO)(μ-H)(μ-PtBu2)(μ-dppm)]+ (2) as reported by us in an earlier paper. Instead always a mixture of three compounds containing the complexes [Ru2(CO)4(μ-H) 2(μ-PtBu2)(μ-dppm)]+ (3), [Ru 2(CO)4(μ-NO)(μ-PtBu2)(μ-dppm)] (4), beside the originally described complex 2 was obtained. A new synthetic procedure affording compound 4 as the sole product by reaction of 1 with the nitrosylating reagent diazald (N-methyl-N-nitroso-p-toluenesulfonamide) is described. It was found that complex 2 can act as an acid strong enough to protonate the starting complex 1. Thus, the formation of the mixture of components in the title reaction could be explained. A mixing experiment of equimolar amounts of 1 and 2 showed unambiguously the formation of complexes 3 and 4. A clean preparation of complex 2 as the sole product in form of its tetrafluoridoborate salt is only possible by reaction of 4 with tetrafluoridoboric acid in diethyl ether solution. The X-ray crystal structure of [2]BF4 is reported confirming the molecular structure of the complex 2. Using the originally described preparation route for 2 afforded in each attempt of crystallization the complexes 2 and 3 as 1:1 mixture in the solid. Copyright

Protonation of metal-metal bonds: X-ray crystal structures of the complex salts [Ru2(CO)4(μ-H)(μ-Cl)(μ-PtBu 2)(μ-Ph2PCH2PPh2)][BF 4] and [M2(CO)4

B?ttcher, Hans-Christian,Graf, Marion,Merzweiler, Kurt,Wagner, Christoph

, p. 144 - 150 (2007/10/03)

Addition of tetrafluoroboric acid to the coordinatively unsaturated species [M2(CO)4(μ-H)(μ-PtBu 2)(μ-dppm)] (M=M) (M=Fe, 1; M=Ru, 2; dppm=Ph2PCH2PPh2) in diethylether results in

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 358971-05-8