359-37-5

Basic information

• Product Name: IODOTRIFLUOROETHYLENE
• Synonyms: IODOTRIFLUOROETHYLENE;Ethene, trifluoroiodo-;Trifluoroiodoethylene;1,2,2-Trifluoro-1-iodoethene;Iodotrifluoroethylene 97%;Iodotrifluoroethylene97%;IODOTRIFLUOROETHYLENE STABILIZED WITH COPPER;Trifluoroiodoethylene, 97%, stab. with copper
• CAS NO: 359-37-5
• Molecular Formula: C₂F₃I
• Molecular Weight: 207.92
• EINECS: 206-629-9
• Mol File: 359-37-5.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 30°C
• Flash Point: 30°C
• Appearance: /
• Density: 2,284 g/cm3
• Vapor Pressure: 636mmHg at 25°C
• Refractive Index: 1.4143
• Storage Temp.: Keep Cold
• Sensitive: Light Sensitive
• BRN: 1740912
• CAS DataBase Reference: IODOTRIFLUOROETHYLENE(CAS DataBase Reference)
• NIST Chemistry Reference: IODOTRIFLUOROETHYLENE(359-37-5)
• EPA Substance Registry System: IODOTRIFLUOROETHYLENE(359-37-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• HazardClass: IRRITANT, GAS, KEEP COLD
• Hazardous Substances Data: 359-37-5(Hazardous Substances Data)

Usage

Uses

Iodotrifluoroethylene is used in preparation method of peroxide-curable fluorine-containing elastomer.

InChI:InChI=1/C2F3I/c3-1(4)2(5)6

Upstream product

• 811-97-2 1,1,1,2-tetrafluoroethane 
• 598-73-2 1-bromo-1,2,2-trifluoroethene 
• 1375484-85-7 N(C₄H₉)4⁽¹⁺⁾*CF₂CFBF₃^(1-)=N(C₄H₉)4[CF₂CFBF₃] 
• 1426-65-9 1,2,2-trifluorovinyl tri-n-butylstannane 
• 56184-59-9 (pentafluoro ethyl) magnesiumbromide 
• 354-26-7 1-chloro-2-iodo-1,1,2-trifluoroethane 
• 1511-68-8 (perfluoro vinyl) difluoro borane 
• 683-78-3 trifluorovinyllithium 
• 354-65-4 1,2-diiodotetrafluoroethane 

Downstream Products

• 384-47-4 3-chloro-1,1,2,4,4-pentafluoro-4-iodo-but-1-ene 
• 110784-76-4 1-Bromo-3,4,4-trifluoro-but-3-en-2-one 
• 110784-72-0 4,4-dimethyl-1,1,2-trifluoro-1-penten-3-one 
• 110784-71-9 4-methyl-1,1,2-trifluoro-1-penten-3-one 
• 389868-23-9 1,2-bis(3-nitrophenyl)hexafluorocyclobutane 
• 594-27-4 tetramethylstannane 
• 759-27-3 tris-trifluorovinyl-phosphane 
• 115-25-3 Octafluorocyclobutane 
• 652-23-3 perfluorostyrene 
• 13557-43-2 1,2-bis(pentafluorophenyl)acetylene 
• 685-63-2 hexafluoro-1,3-butadiene 
• 434-90-2 decafluorobiphenyl 
• 1165953-25-2 [OC-6-32]-[Rh(CF₃)(trifluorovinyl)I(2,6-dimethylphenyl isocyanide)(PMePh₂)2] 
• 392-52-9 trans-octafluoro-1,3,5-hexatriene 

Relevant articles and documents

The stereospecific preparation of two perfluoro-1,3-butadiene synthons; (E)-1-trimethylsilyl-1,2,3,4,4-pentafluoro-1,3-butadiene and (E)-1-tributylstannyl-1,2,3,4,4-pentafluoro-1,3-butadiene

(E)-1-Trimethylsilyl-1,2,3,4,4-pentafluoro-1,3-butadiene (1) can be stereospecifically prepared by Pd(0)/CuI catalyzed cross-coupling of (Z)-1-tributylstannyl-1,2-difluoro-2-trimethylsilylethene with iodotrifluoroethene. The corresponding (E)-1-tributylst

The stereoselective synthesis of (E)-octafluoro-1,3,5-hexatriene and (3E,5E,7E)-dodecafluoro-1,3,5,7,9-decapentaene

(E)-(1,2-Difluoro-1,2-ethenediyl)bis[tributylstannane], 3, readily undergoes a Pd(PPh3)4/CuI-catalyzed cross-coupling reaction with iodotrifluoroethene to yield (E)-octafluoro-1,3,5-hexatriene, 4, in high isomeric purity. (1Z,3E,5Z)-

Reactions of perfluorinated alkenyl-, alkynyl-, alkyltrifluoroborates, and selected hydrocarbon analogues with the halogenating agents Hal2 (Hal = F, Cl, Br), "brF" (BrF3-Br2 1:1), and ICl

Reactions of [Bu4N][RBF3] [R = CnF 2n+1CF=CF (cis, trans), CF2=CF, CF2=C(CF 3), trans-C4H9CF=CF, trans-C6H 5CF=CF, C4H9CH=CH (cis, trans), CF 3C≡C, and C4H9C≡C] with chlorine, bromine, BrF3 + Br2 (as equivalent of "BrF"), and ICl in solution (CH2Cl2, CHCl3, CF 3CH2CF2CH3) led to 1, 2-addition of halogen and/or replacement of boron by halogen (halodeboration). The reaction of [Bu4N][CF3C≡CBF3] with less than equimolar amounts of diluted fluorine (5 %) in 1, 1, 1, 3, 3-pentafluorobutane (PFB) showed only [Bu4N][CF3CF2CF 2BF3] as fluorine addition product besides extensive fluorodeboration. Suspensions of the insoluble K[CF2=CFBF 3] salt reacted with Cl2 and Br2 in CH 2Cl2 giving preferentially products of halogen addition across the C=C bond. In reactions with ICl iododeboration with formation of CF2=CFI occurred besides 1, 2-addition with formation of [CF 2I-CFClBF3]-. The halodeboration reaction of[Bu4N][trans-C4H9CF=CFBF3] with Br2, "BrF", and ICl, of K[trans-C6H 5CF=CFBF3] with Br2, and of [Bu 4N][trans-C4F9CF=CFBF3] with ICl proceeded stereospecifically. Copyright

CHEMICAL PRODUCTION PROCESSES AND SYSTEMS

Chemical production processes are provided that include reacting a metal comprising olefin to form a conjugated olefin; reacting a heterohalogenated olefin to form a conjugated olefin; reacting a halogenated alkane to form a conjugated olefin; and/or reacting a hydrohalogenated olefin to form a conjugated olefin. Chemical production systems are also provided that can include: a first reactant reservoir configured to house a perhalogenated olefin; a second reactant reservoir configured to house a catalyst mixture; a first reactor coupled to both the first and second reservoirs, the first reactor configured to house a metal-comprising mixture and receive both the perhaloganated olefin form the first reactant reservoir and the reactant mixture from the second reactant reservoir; and a product collection reservoir coupled to the first reactor and configured to house a conjugated olefin.