359012-05-8Relevant academic research and scientific papers
Rapid screening of a receptor with molecular memory
Lavin, Judith M.,Shimizu, Ken D.
, p. 2389 - 2392 (2006)
Atropisomeric receptor 1 can change conformation and maintain the new conformation when heated and cooled in the presence of a guest molecule. This molecular memory can be used as a rapid method of screening potential guests. Heating atropisomeric diacid
Guest control of a hydrogen bond-catalysed molecular rotor
Rushton, Gregory T.,Vik, Erik C.,Burns, William G.,Rasberry, Roger D.,Shimizu, Ken D.
supporting information, p. 12469 - 12472 (2017/11/22)
Herein, the control of a molecular rotor using hydrogen bonding guests is demonstrated. With a properly positioned phenol substituent, the N-arylimide rotors can form an intramolecular hydrogen bond that catalyses the rotational isomerization process. The
Solvent-induced reversible solid-state colour change of an intramolecular charge-transfer complex
Li, Ping,Maier, Josef M.,Hwang, Jungwun,Smith, Mark D.,Krause, Jeanette A.,Mullis, Brian T.,Strickland, Sharon M. S.,Shimizu, Ken D.
supporting information, p. 14809 - 14812 (2015/10/05)
A dynamic intramolecular charge-transfer (CT) complex was designed that displayed reversible colour changes in the solid-state when treated with different organic solvents. The origins of the dichromatism were shown to be due to solvent-inclusion, which induced changes in the relative orientations of the donor pyrene and acceptor naphthalenediimide units.
Covalent locking and unlocking of an atropisomeric molecular switch
Chong, Yong S.,Dial, Brent E.,Burns, William G.,Shimizu, Ken D.
supporting information; experimental part, p. 1296 - 1298 (2012/03/08)
Demonstrated is the reversible switching and saving of a conformational molecular switch via heating in different environments followed by reversible chemical entrapment. The Royal Society of Chemistry 2012.
A high-barrier molecular balance for studying face-to-face arene-arene interactions in the solid state and in solution
Chong, Yong S.,Carroll, William R.,Burns, William G.,Smith, Mark D.,Shimizu, Ken D.
experimental part, p. 9117 - 9126 (2010/04/25)
An atropisomeric molecular balance was developed to study faceto-face arene-arene interactions. The balance has a large central 1,4,5,8naphthalene diimide surface that forms intramolecular arene-arene interactions with two pendent arms. The balance adopts
